1 g of a moist sample of a mixture of KCIO and KCI was

Last updated: 7/3/2023

1 g of a moist sample of a mixture of KCIO and KCI was dissolved in water and made upto 250 mL 25 mL of this solution was treated with SO to reduced chlorate into chloride and the excess SO was boiled off When the total chloride was precipitated 0 1435 g of AgCl was obtained In another experiment 25 mL of the original solution was treated with 30 mL of 0 2 N solution of FeSO and unreacted FeSO required 37 5 mL of 0 08 N solution of an oxidizing agent for complete oxidation Calculate the molar ratio of chlorate and chloride in the given mixture Fe reacts with CIO according to equation CIO 6Fe 6HCl 6Fe 3H O 3