Organic Chemistry Questions
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Organic Chemistry
Aldehydes & KetonesDetermine the principal product of the following reaction ei O O O 1 LDA THF 15 C 2 CH3 CHCH Br The zi
Organic Chemistry
Reactions of benzeneWhich series of reagents would be required to perform the following synthesis O 1 Cl AICI 3 2 CH3CH CH COCI AICI 3 3 NH2NH2 KOH A O 1 CH3CH CH CH CI AICI3 2 Cl2 AICI3 O 1 CH3CH CH COCI AICI 3 2 NH2NH2 KOH A 3 Cl2 AICI 3 O 1 CH3CH CH COCI AICI 3 2 Cl2 AICI 3 3 NH NH KOH A
Organic Chemistry
Alcohols and PhenolsWhat is the starting material for the reaction below O II OI SO IV 11 NaOH OH IV
Organic Chemistry
General organic chemistryWhat is the major product of this reaction O O H N NC HOOC OH OH OH CN 1 NaCN HCI 2 H H O
Organic Chemistry
General organic chemistryWhat is the full electron configuration for sillicon O 1s 2s 2p 3s 3p O 1s 2s 2p 3s 3p4 O 1s 2s 2p63p4
Organic Chemistry
General organic chemistryClassify the following as a physical or chemical change A log burning in a fireplace chemical
Organic Chemistry
Alcohols and PhenolsWhat starting material with these reagents will result in 3 3 4 4 tetrabromoheptan 1 PBr3 2 NaCEC 3 Br excess O O O OH OH OH OH Br Br Br Br
Organic Chemistry
General organic chemistryWhich is the strongest nucleophile in a polar aprotic solvent such as acetone CH3CO Na CH3SNa CF3ONa CH3ONa
Organic Chemistry
IsomerismWhat is the IUPAC name of this structure CH3 H3C LOH O 1 fluoro 6 ethylheptan 3 ol O 7 fluoro 2 ethyl heptan 5 ol O 7 fluoro 3 methyloctan 6 ol O 1 fluoro 6 methyloctan 3 ol
Organic Chemistry
Chemistry in Daily LifeThe half life of a radioisotope is 2 04 x 103 yr How many years will it take for a 289 g sample to decay until 103 g of the isotope remains Enter your answer as an integer
Organic Chemistry
General organic chemistryHow many valence electrons does Carbon have Question 73 How many valence electrons does Cobalt have
Organic Chemistry
Reactions of benzeneTrying to attach the aromatic ring Give them missing reactant or reactants please type out your explanation Trying to attach the aromatic ring Give the missing reactant or reactants BOR
Organic Chemistry
General organic chemistry7 Synthesis Design a reasonable synthesis for the following R NOTE You can use any other inorganic and organic reagents The molecules below are a set of a possible intermediate set to go through in the synthesis It is not required that you make the molecules below in your synthesis OH OH
Organic Chemistry
General organic chemistryA chemical reaction rate compares a the concentration of the reactants to the rate of the reaction b the temperature of the reactants to the rate of the reaction c the concentration of the products to the concentration of the reactan d the surface area of the reactants to the rate of the reaction
Organic Chemistry
Chemistry in Daily LifeWhich of the following elements would have similar physical and chemical properties AI Co Be B
Organic Chemistry
Practical DetectionWhat is the multiplicity of the protons on the indicated carbons in the H NMR spectrum O I doublet II singlet III singlet OI doublet II doublet III singlet OI singlet II singlet III singlet OI singlet II doublet III singlet
Organic Chemistry
General organic chemistryIn the H C N molecule the hybridization of carbon is of nitrogen is OA sp sp OB s p sp OC sp sp O D sn sn and the hybridization
Organic Chemistry
General organic chemistryWhat is the correct combination of A B and C HH HH A HBr CCI B C A H Pt C ethanol B Na NH3 C 1 BH3 THF 2 H O2 NaOH O A H Pd BaSO4 B LINH2 NH3 C HgSO4 H SO4 O A Na NH3 B NaNH2 NH3 C 1 R BH THF 2 H O2 NaOH A Li NH3 B NaOtbu C 1 Hg OAc 2 H O 2 NaBH4 3 PCC 2
Organic Chemistry
General organic chemistryWhich of the following compounds will produce a carboxylic acid when treated first with Br in NaOH and then acidic wor
Organic Chemistry
General organic chemistryWhat is the abbreviated noble gas configuration for Gallium O Ar 3d10 4p3 Ar 4s2 3d10 O Ar 4s 3d 10 4p O Ar 4s 4p O Ar 4s 3d10 4p 27
Organic Chemistry
Aldehydes & KetonesWhich structure is consistent with this mass spectrum O Rel Intensity 100 80 60 O OH 40 20 OH CHO 0 0 20 40 55 m z 60 80 98 100
Organic Chemistry
General organic chemistryChoose the best description for the selectivity specificity of the transformation shown below Br V V Bri stereospecific O both stereospecific and regioselective neither stereospecific nor regioselective regioselective
Organic Chemistry
Chemistry in Daily LifeIs the mass of 129 531 identical to the atomic mass of iodine O no O No answer text provided yes
Organic Chemistry
Alcohols and PhenolsWhat is the product in the following reaction OH O O CN CN OH 3 CN 1 SOCI 2 NaCN
Organic Chemistry
General organic chemistryWhat kind of compound is CO A Non polar molecule with polar bonds B polar molecule with non polar bonds OC ionic OD Polar molecule with polar bonds
Organic Chemistry
General organic chemistryWhich represents an initiation step of a radical reaction R O O R 2 OR OR 2 OR R R O O R OR
Organic Chemistry
HydrocarbonsWhich is are the product s of the following reaction Olonly OI and III II and IV O III only Br OCH3 CH OH II OH OCH3 IV Oli OH
Organic Chemistry
Chemistry in Daily LifeWhat pressure in atm will a sample of O2 gas occupy at 100 0 mL if O has a volume of 25 00 mL at 2 0 atm A 4 0 atm OB 2 0 atm OC 0 50 atm OD 125 atm
Organic Chemistry
General organic chemistryWhat are the bond angles associated with the indicated atoms HO H II III O1 109 5 II 109 5 III 120 O1 107 11 105 III 105 OI 105 II 120 III 180 01 105 11 109 5 III 109 5
Organic Chemistry
Practical DetectionConsider the reaction 8 H S g 4 O g 8 H O g Sg g The average rate of consumption of O is 18 9 M s over the first two minutes What is th average rate of formation in M s of Sg during the same time interval Enter your answer to 2 decimal places
Organic Chemistry
General organic chemistryWhat is the full electron configuration for bromine O 15 25 2p 3s 3p 3d 0 4s 4p O 1s 25 2p 3s 3p 3d 0 4s 4p5 O 1s 2s 2p O 1s 2s 2p O 1s 25 2p 3s 3p 3d 4s 4p6 3s 3p6 4s 4p5 3s 3p 3d 0 4s 4p
Organic Chemistry
General organic chemistryPart 2 Practice Problems Follow steps 1 5 to illustrate the synthesis of the following alcohols a dipropyl ether Step 1 Draw Kekule structures of the reagents Step 2 Mark reacting atoms group or bonds Step 3 Indicate proton and hydroxide groups to be removed Step 5 Write the complete equation using a Kekule structures b Condensed formula c Line angle formula b diisobutyl ether Step 1 Draw Kekule structures of the reagents Step 2 Mark reacting atoms group or bonds Step 3 Indicate proton and hydroxide groups to be remove Step 4 Write Kekule structure of the product
Organic Chemistry
HydrocarbonsCalculate the atomic mass of element X if it has 2 naturally occurring isotopes with the following masses and natural abundances X 45 X 47 44 8776 amu 46 9443 amu OA 46 84 amu OB 46 34 amu C 45 91 amu OD 46 26 amu 32 88 67 12
Organic Chemistry
General organic chemistryWhat is the strongest type of intermolecular force present in CHF3 A ion dipole B hydrogen bonding C dipole dipole D dispersion
Organic Chemistry
General organic chemistryGive the set of four quantum numbers that could represent the last electron added using the Aufbau principle to the Cl atom A n 3 1 1 ml 1 m 1 2 B n 2 1 ml 1 m 1 2 C n 3 1 0 ml 1 m 1 2 OD n 3 1 2 ml 1 m 1 2
Organic Chemistry
Carboxylic acidsSelect the reagents that can carryout the following transformation loc OC H5 O CH3 2 CHCH OH with HCI aq catalyst O CH3 2C CH in presence of acid catalyst O NaOC H5 followed by CH3 2 CHCH Br O NaOC H5 followed by CH3 2 CHCH OH OC H5
Organic Chemistry
HydrocarbonsStep 1 Draw Kekule structures of the reagents Step 2 Mark reacting atoms group or bonds Step 3 Indicate directions of the substitutions apply Markovnikov s rule Step 4 Write Kekule structure of the product Step 5 Write the complete equation using a Kekule structures b Condensed formula la formula
Organic Chemistry
Chemistry in Daily LifeWhat is the abbreviated noble gas configuration for Cobalt O Ar 3d O Ar 4s 4p7 O Ar 4s 3d7 O Ar 3d7 4s24p
Organic Chemistry
Practical DetectionUse the information and samples to answer the following question The process of freezing is shown for two samples The smaller circles represent a solute Which statement predicts and explains which would have the lowest freezing point Sample A has the lowest freezing point because more energy must be removed to have the particles line up in a solid arrangement Sample A has the lowest freezing point because to have the particles packed close together you need to have only one type of particle or solute Sample B has the lowest freezing point because the solute particles interfere with the attractive forces among the solvent particles Sample B has the lowest freezing point because the solute particles freeze at a lower temperature
Organic Chemistry
General organic chemistryFor the following reaction which of the following change s in the IR spectrum is consistent with conversion of the reactant to the product H CH CCECH 1 NaNH 2 CH CH Br H CH CC CCH CH3 O Absorption at 2250 cm 1 should disappear a new sharp absorption at 3300 cm 1 should appear O Absorption at 1650 cm 1 should disappear a new sharp absorption at 3300 cm 1 should appear O Sharp absorption at 3300 cm 1 should disappear Sharp absorption at 3300 cm 1 should disappear a new absorption at 1720 cm 1 should appear
Organic Chemistry
Hydrocarbons29 Write structures for the following bicyclic alkanes a Bicyclo 1 1 0 butane b Bicyclo 2 1 0 pentane c 2 Chlorobicyclo 3 d 7 Methylbicyclo
Organic Chemistry
General organic chemistryMolecular compounds are usually A Composed of positive and negative ions B Composed of two or more transition elements C Composed of metal and nonmetal D Composed of two or more nonmetals
Organic Chemistry
EthersFollow steps 1 5 to illustrate the synthesis of the following alcohols a dipropyl ether Step 1 Draw Kekule structures of the reagents Step 2 Mark reacting atoms group or bonds Step 3 Indicate proton and hydroxide groups to be removed
Organic Chemistry
Chemistry in Daily LifeHow many unpaired electrons are in an atom of Cu in its ground state OA 2 B 3 OC 1 OD 9
Organic Chemistry
HydrocarbonsCalculate the number of tetraphosphorus hexoxide molecules in a 16 8 g sample
Organic Chemistry
IsomerismWhat is the major product of this reaction 1 equiv HCI 80 C 8 O CI CI z CI