Organic Chemistry Questions
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Organic Chemistry
Practical DetectionIf 4.00 L of water vapor at 50.2 °C and 0.121 atm reacts with excess iron, how many grams of iron(III) oxide will be produced?
2 Fe(s) + 3 H₂O(g)-->Fe₂O₂ (s) + 3 H₂(g)
Organic Chemistry
Chemistry in Daily LifeA 0.856 mol sample of Kr gas is confined in a 21.9 liter container at 39.2 °C. If the volume of the gas sample is increased to 43.9 L holding the temperature constant, the average force per molecule-wall collision will
not enough information to answer the question
increase
remain the same
decrease
Organic Chemistry
General organic chemistryWhich is the correct net ionic equation for the formation of calcium
oxalate kidney stones?
Ca²+ (s) + C₂04² (s)--> CaC204(aq)
Ca²+ (aq) + C₂04² (aq) -->CaCO3(s)
Cat (aq) + C2O4 (aq) -->CaC₂O4(s)
Ca2+(aq) + C₂04² (aq)-->CaC₂O4(s)
Organic Chemistry
General organic chemistryUpload the model and line formula for Benzoic acid (a benzene ring with COOH attached to one C in the ring). Benzoic acid is insoluble in water but soluble in aqueous sodium hydroxide. Explain mentioning the appropriate IMFs. Hint see canvas lecture Draw the condensed or line formula for sodium benzoate (the benzoic acid deprotonated and a sodium ion counterion) Benzene- COO- Na+
Organic Chemistry
Chemistry in Daily LifeDiazirines (H₂CN2) is a class of reactive organic chemical that, when irradiated with
ultraviolet light, will form "carbene." Give a plausible Lewis structure of H₂CNN.
Organic Chemistry
Practical DetectionIf standard heat of formation of CO₂ is - 400 kJ/mol. The amount of C(graphite) required, if 10 kJ heat is released during the combustion, is g.
Organic Chemistry
Chemistry in Daily LifeA 2 L vessel contains 4 g of Helium and 4 g of H₂ gas at 27°C. After sometime, 50% of the gas having higher average speed is removed. The percentage reduction in total pressure if temperature remains constant is equal to __
Organic Chemistry
HydrocarbonsDraw the E isomer for
CH3CH₂CH=CHCH3
Draw the molecule on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default.
Organic Chemistry
General organic chemistryOne mole of an alkene (E) on ozonolysis gives two different compounds X and Y. X and Y are the isomers of each other and their molar mass is
equal to 58 u, each. Identify the incorrect statement.
X and Y are metamers of each other
Both X and Y can show tautomerism
Compound (E) cannot show geometrical isomerism
The number of hyperconjugable H's in (E) is 8
Organic Chemistry
General organic chemistryWrite a balanced equation with the smallest whole number coefficients and include phases, for each
of the following reactions.
a) The combustion of gaseous butane, C4H10, to form gaseous carbon dioxide and water vapor.
b) Aqueous sodium phosphate and aqueous barium bromide react to form aqueous sodium bromide
and solid barium phosphate.
c) Solid iron (II) carbonate reacts with diatomic oxygen gas to form solid iron(III) oxide and carbon
dioxide gas.
Organic Chemistry
Chemistry in Daily LifeAmong PbS, CdS, As₂S3, CuS, HgS, Ag₂S, NiS, COS, Bi₂S3, SnS₂, ZnS
a is number of black colour sulphide
b is number of white colour sulphide
c is number of yellow colour sulphide
a²-b/c
Find the value of
Organic Chemistry
Practical DetectionTwo elements,
R and
Q, combine to form two binary compounds. In the first
compound, 28.0 g of
R combines with 3.00 g of
Q. In the second compound, 7.00 g of
R combines with 4.50 g of
Q. Show that these data are in accord with the law of
multiple proportions. If the formula of the second
compound is
RQ, what is the formula of the first compound?
Compound I:||
Organic Chemistry
Practical DetectionA chemist makes 490. mL of potassium permanganate (KMnO4) working solution by adding distilled water to 110. mL of a 0.391 mol/L stock solution of
potassium permanganate in water. Calculate the concentration of the chemist's working solution. Round your answer to 3 significant digits.
Organic Chemistry
General organic chemistryWhich choices are correct explanations about the scanning electron microscope (SEM)? (Select all that apply.)
Useful resolution range for SEM is much narrower than the optical microscopes.
SEM can investigate non conductive samples as good as the conductive ones.
Samples for SEM do not need to be polished nor etched.
Electron beam is the main light source for SEM.
The condensed beam needs to pass through the specimen to obtain the picture for SEM.
Organic Chemistry
Practical DetectionWhat is the mass number for an atom of molybdenum containing 42 protons and 53 neutrons?
Organic Chemistry
Biomolecules2. Draw the structure of isoleucine and determine the charge on a molecule in a(n)
a. Acidic solution (pH= 1)
b. Neutral solution (pH = 7)
c.Basic solution (pH = 11)
Organic Chemistry
HydrocarbonsDescribe how soap works in detail. What interactions are in play and between what?
Organic Chemistry
Practical DetectionIf you added Na2CO3 to Hcl bubbles would be formed on adding the two reeactants. If you lit a match in the neck of the test tube the flame would immediately be extinguished. Based on the above observations, answer the following questions:
a. What evidence is there of a chemical reaction?
b. What caused the change in the burning match or split?
c. Write a balanced equation for this reaction.
d. What type of chemical reaction is this?
Organic Chemistry
BiomoleculesWith respect to superoxide dismutase,
it produces superoxide
it employs a ping-pong mechanism of action
it uses oxidized molecular oxygen
all of the above are true
none of the above are true
Organic Chemistry
General organic chemistryAmmonia will react with fluorine to produce dinitrogen tetrafluoride and hydrogen fluoride as follows:
2NH 3(g) + 5F 2(g) → N ₂F 4( g) + 6HF( g)
How many moles of NH 3 are needed to react completely with 13.6 mol of F ₂?
27.2 mol
34.0 mol
5.44 mol
2.27 mol
6.80 mol
Organic Chemistry
Chemistry in Daily LifeWhen a single compound breaks up into two or more components, it is called a______reaction
► View Available Hint(s)
decomposition
combustion
combination
single replacement
Organic Chemistry
General organic chemistryCalculate the AH of a reaction with bond strengths of bonds broken equal to 60 kcal/mol and 107 kcal/mol and bond strengths of bond formed equal to 110 kcal/mol and 88 kcal/mol.
-245 kcal/mol
151 kcal/mol
31 kcal/mol
-31 kcal/mol
Organic Chemistry
Practical DetectionWhich of the following correctly summarizes the Pauli Exclusionary Principle?
Each electron within an atom will have its own unique set of four quantum numbers.
Electrons orbiting an atom fill the lowest available energy levels prior to filling higher energy orbitals.
Matter can neither be created nor destroyed. It only changes form during chemical reactions. The ground state or lowest energy state of an atom is the one that contains the maximum number of unpaired electrons.
It is fundamentally impossible to know both the location and velocity of an electron at the same time.
Organic Chemistry
General organic chemistryThe factors that most commonly cause chemical reactions to occur are all the following except
a. formation of a solid
b. formation of a gas
c. formation of water
d. transfer of electrons
e. a decrease in temperature
Organic Chemistry
Practical DetectionSolid manganese (IV) oxide reacts with solid aluminum metal to produce solid manganese and solid aluminum oxide. Balance the equation for this reaction (in lowest multiple integers).
Organic Chemistry
Chemistry in Daily LifeWrite a balanced equation for the combination reaction described, using the smallest possible integer coefficients.
When hydrogen combines with iodine, hydrogen iodide is formed.
Organic Chemistry
Chemistry in Daily LifeWhen 7.70 g of hydrocarbon (molar mas = 341.7 g/mol) is burned in a bomb calorimeter, the calorimeter increases in temperature by 2.32°C. If the heat capacity of the bomb calorimeter is 1.356 kJ/°C, what is the heat of combustion for the hydrocarbon, in kJ/mol?
Organic Chemistry
General organic chemistryWhich of the following is incorrectly named?
Pb(NO3)2, lead(II) nitrate
NH4CIO4, ammonium perchlorate
PO4, phosphate ion
Mg(OH)2, magnesium hydroxide
NO³-, nitrite ion
Organic Chemistry
Practical DetectionAn experiment is set up to determine the type of radioactive decay coming from a certain hazardous nuclide. The analytical instrument used in this experiment detects the charge of the particles emitted from the nuclide. When interpreting the results of the experiment, it was discovered that the emitted particles had no charge at all. Which of the following could be the identity of these particles?
Select the correct answer below:
Positrons
Protons
y particles
β particles
Organic Chemistry
General organic chemistryIn sickle cell anemia, a mutation occurs and glutamic acid is replaced by valine. What effect would you expect to observe?
Since glutamic acid is a polar and valine is nonpolar, the protein would now change its orientation and move towards the interior in aqueous solution.
Since glutamic acid is a polar and valine is nonpolar, the protein would now change its orientation and move towards the exterior in aqueous solution.
Since glutamic acid and valine are both nonpolar amino acids, both residues would move toward the interior in aqueous solution.
Since glutamic acid and valine are both polar amino acids, both residues would move towards the exterior in aqueous solution.
Organic Chemistry
General organic chemistryAmmonia is produced from the reaction of nitrogen and hydrogen according to the following balanced equation:
N₂(g) + 3H₂(g) → 2 NH3(g)
a What is the maximum mass of ammonia that can be produced from a mixture of 1.20 x 10³ g N₂ and 5.70 x 10² H₂?
Organic Chemistry
General organic chemistryA soda bottle is found to have a length of 0.321 meters. Using unit analysis, show what the length of the soda bottle is in feet.
Use one of the following to set up the conversion factor.
454 g 1 lb 16 oz
1 m39.4 in= 3.28 feet
2.54 cm= 1 in
1 km 0.621 miles
1 L=1.06 qt
3.79 L=1 gal
Organic Chemistry
Chemistry in Daily LifeWhat should be the H-NMR multiplicity for a proton (type A) with 3 different protons (types B, C, and D) in its adjacency?
quartet
triplet
doublet of a triplet
doublet of a doublet
Organic Chemistry
General organic chemistrya. 1,2,5-trimethylcyclohexane
b. 3-bromo-1-octyne
c. o-iodotoluene
d. pichlorophenol
e. cis-2-isopropylcyclobutanol
f. 2,3-dibromocyclohexene
g. trans-4-methylcycloheptanol
h. 3-methyl-3-pentanol
Organic Chemistry
Practical DetectionSeveral steps are involved in the industrial production of sulfuric acid. One step involves the oxidation of sulfur dioxide gas to form sulfur trioxide gas. A catalyst is used to increase the rate of production of sulfur trioxide gas. In a rigid cylinder with a movable piston, this reaction reaches equilibrium, as represented by the equation below.
2SO₂(g) + O₂(g) →2SO3(g) + 392 kJ
A. Explain in terms of collision theory, why increasing the pressure of the gases in the cylinder increases the rate of the forward reaction.
B. State, in terms of the concentration of SO3(g), what occurs when the following changes are made to the equilibrium mixtures.
i. More O₂(g) is added.
ii. SO3(g) is removed.
C. If 40 grams of sulfur trioxide gas, SO3(g) was passed through 250 mL of water, determine the olarity of sulfuric acid formed.
Organic Chemistry
PolymersDraw the structure of each amino acid below at low pH (pH= 1), pH = 7.4 and high pH (pH = 14) and classify it as polar or nonpolar. If polar, indicate if the R group is neutral, acidic or basic. Indicate if each is hydrophobic or hydrophilic.
a. lysine
b. proline
c. valine
d. tyrosine
Organic Chemistry
HydrocarbonsPredict the major product of this organic reaction:
CH3—CH=CH-CH3 + H2O -> H+ ?
Organic Chemistry
BiomoleculesA bottle contained 27.0 mL of a concentrated solution. Water was added to a new volume of 762 mL and the concentration of the diluted solution is 0.444 M. What was the molarity of the concentrated solution?
Organic Chemistry
PolymersWhat is the theme of this poem?
Beauty always gives Joy.
One has to lead a spiritual life.
The thoughts of people change as the season does.
Beauty can be used to raise the spirits in times of gloom.
Organic Chemistry
General organic chemistryAn aqueous magnesium chloride solution is made by dissolving 5.50 moles of MgCl, in sufficient water so that the final volume of the solution is 3.60 L. Calculate the molarity of the MgCl₂ solution.
Organic Chemistry
Practical DetectionAssume you are trying to extract pure iron (Fe) from a sample of Fe2O3. What mass (in grams) of iron can be extracted from 75.0 grams of Fe2O3?
Organic Chemistry
General organic chemistryWhich of the following is true about small and stable nuclei?
They contain an odd number of neutrons
They contain an equal number of protons and neutrons
They contain an odd number of protons
They contain an even number of protons
Organic Chemistry
Practical DetectionIron (III) oxide reacts with carbon monoxide according to the equation:
Fe2O3(s) + 3 CO(g) → 2 Fe(s) + 3 CO2(g)
a) If 22.55 g Fe2O3 is reacted with excess CO, how many grams of iron can be made?
b) If we want to refine 10.0 kg of iron metal, how many moles of carbon monoxide gas do we need?
c) If 2.50 moles of Fe2O3 is reacted with carbon monoxide, how many liters of carbon dioxide gas form?
Organic Chemistry
General organic chemistryThe structure below is a(n) .....
CH3COCH3
A. ether; dimethyl ether; ether
B. aldehyde; propanal; acetone
C. ketone; propanone; acetone
D. ketone; acetone; propanone
E. ether; propane oxide; acetone
with the IUPAC name......
and the common name
Organic Chemistry
General organic chemistryThe incomplete combustion of propane gas produces among others
A. soot and hydrogen gas
B. soot and carbon monoxide
C. carbon dioxide and hydrogen peroxide
D. aromatic hydrocarbon and sulfur
E. sulfur and nitrogen oxides
Organic Chemistry
General organic chemistryConsider equal mole samples of dinitrogen monoxide, aluminum nitrate, and potassium
cyanide. Rank these from least to greatest number of nitrogen atoms in each sample.
potassium cyanide, dinitrogen monoxide, aluminum nitrate
aluminum nitrate, potassium cyanide, dinitrogen monoxide
dinitrogen monoxide, aluminum nitrate, potassium cyanide
potassium cyanide, aluminum nitrate, dinitrogen monoxide
Organic Chemistry
General organic chemistryAccording to Emerson in
Section 6 of "Nature," in what
way does nature (e.g., going
to the woods) restore our
faith?
A. It causes us to believe that we can
slough off old age and become little
children again.
B. It causes us to believe that nothing can
happen to us in life that "nature" cannot
repair.
C. It causes us to believe that if we just
stay in the woods, everything will be like a
festival.
Organic Chemistry
General organic chemistryIf you were writing that one
of Emerson's purposes in
writing "Self-Reliance" was to
convince his readers to be
themselves, which passage
from the text would you cite
to best support your thesis?
A. Sec 7: I ought to go upright and vital,
and speak the rude truth in all ways.
B. Sec 2: This sculpture in the memory'is
not without preestablished harmony.
C. Sec. 6: The only right is what is after
my constitution; the only wrong what is
against it.
Organic Chemistry
General organic chemistryThe radius of a uranium atom is 149 pm. How many uranium atoms would have to be laid side by side to span a distance of 1.15 mm?
Organic Chemistry
Practical Detection4. How many grams of acetylene would be given off if the limiting reagent in the reaction is calcium
carbide and you start with 2.00 g?
molar mass CaC₂ = 64.1 g/mol molar mass C₂H₂ = 26.0 g/mol
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