Hydrocarbons Questions and Answers
Organic Chemistry
HydrocarbonsWhat product s would you expect from the following reaction CH3 NBS Br CCl4 hv You do not have to consider stereochemistry If more than one structure fits the description draw them all Draw one structure per sketcher Add additional sketchers using the drop down menu in the bottom rig Separate structures with signs from the drop down menu
Organic Chemistry
HydrocarbonsDetermine the degrees of unsaturation for a molecule with a molecular formula of C5H7N₂OCI (1.5 points). Then draw a Lewis structures of the molecule that includes a Ring and an Aldehyde (3.5 points). All atoms must have a formal charge of ZERO. Include all atoms and lone pairs and draw proper bond angles. There are multiple correct answers.
Organic Chemistry
HydrocarbonsUsing an alcohol of no more than 4 carbon atoms as your only organic starting material (other inorganic materials such as Mg, PBr3, reducing reagents and oxidizing reagents all can be used), outline a synthesis route to the following molecule. Note: The alcohol can be used multiple times.
Organic Chemistry
HydrocarbonsFernando is doing his pre-lab homework for Chemistry. He is asked to predict how many grams of CO2 are produced if 2.09 mol of HCI are reacted according to this balanced
chemical equation shown.
CaCO3 + 2HCI → CaCl2 + CO2 + H2₂O
He performs the following calculation.
1 mol CO₂
2 metHCI
2.09 metHCT x
X
from the coefficients
of the balanced
equation
44.01 g CO₂
1 mol CO₂
= 46.0 g CO₂
On the day of the lab his group obtains 43.1 grams of CO2 as their experimental result. What is their percent yield?
round your answer to the tenths place, i.e. one decimal place
Organic Chemistry
HydrocarbonsStarting with 2-bromobutane, which of the following reagents would you use to produce 1-butene as the major product?
1.
2.
3.
4.
1) CH₂CH₂ONA / CH₂CH₂OH
2) ((CH₂)CH)₂NLi / ether
3) CH₂SNa / acetone
4) CH₂CO₂Na/CH₂CO₂H
Organic Chemistry
HydrocarbonsWhat coefficients would result in the below chemical equation
being balanced? (The coefficients in the answers are written in the
same order as they would be placed into the chemical equation.)
Chemical Equation:
_Al(s) + HCl(aq) --> ___AICI3(s) +___H2(g)
4,16,4,6
2,6,3,2
2,6,2,3
1,3,1,1
O2,3,1,1
Organic Chemistry
HydrocarbonsM/ Ch. Hydrohalogenation involves the reaction of an alkene with which of the following?
hydrogen
a hydrogen halide
a halogen
water
Organic Chemistry
Hydrocarbons1,2-Dichloropentane reacts with excess sodium amide in liquid
ammonia (followed by water workup) to produce compound X. Com-
pound X undergoes acid-catalyzed hydration to produce a ketone.
Draw the structure of the ketone produced upon hydration of com-
pound X.
Organic Chemistry
HydrocarbonsA compound with molecular formula C6H₁0 gives three signals in its 1H NMR spectrum with the following integration values measured in mm: 13, 33, 73. a) How many protons are responsible for each signal? b) Deduce the structure of this compound.
Organic Chemistry
HydrocarbonsCalculate the mass of butane needed to produce 96.0 g of carbon dioxide.
Express your answer to three significant figures and include the appropriate units.
Organic Chemistry
HydrocarbonsA sample of propane, C3H8, contains 17.9 moles of carbon atoms. How many total moles of atoms does the sample contain?
Express the total number of moles of carbon and hydrogen numerically.
Organic Chemistry
HydrocarbonsHow many electrons are in energy level 3 of the
following elements?
a. argon
b. carbon
Organic Chemistry
HydrocarbonsWrite the structural formula for the product that forms when 1-methylcyclopentene reacts with Br₂ in H₂O. Include stereochemistry in your answer. Draw only one enantiomer.
Note: All structures should be drawn with no bonds between carbon and hydrogen.
Organic Chemistry
HydrocarbonsHow would adding lye (NaOH) to the sink drain remove the blockage?
Adding NaOH will saponify lipids, forming glycerol and salts of the fatty acids that are soluble in water and would wash down the drain.
Adding NaOH will saponify lipids, forming glycerol and salts of the fatty acids that are soluble in nonpolar organic solvents.
Adding NaOH will decompose lipids, forming CO₂ and H₂O.
Adding NaOH will saponify lipids, forming ethylene glycol and salts of the fatty acids that are soluble in water and would wash down
the drain.
Organic Chemistry
HydrocarbonsHow does the structure of the peptide bond make the structure of proteins relatively rigid? Select the single best answer.
The R groups on adjacent amino acids are on opposite sides of the extended peptide chain,
adding to the rigidity.
The double bond between carbon and oxygen restricts free rotation.
The bond between hydrogen and nitrogen restricts free rotation.
The partially double bonded character of the resonance structure restricts free rotation.
Organic Chemistry
HydrocarbonsCompound X reacts with HI. The product of this reaction, when treated with KOH in ethanol, gives Y ( an isomer of X).
Ozonolysis of Y (H₂O2 workup) produces two compounds: a two carbon carboxylic acid, and a four carbon ketone.
What is X?
A) 2-methyl-2-pentene
B) 4-methyl-1-pentene
C) 2,3-dimethyl-2-butene
D) 3-methyl-1-pentene
Organic Chemistry
HydrocarbonsThe IUPAC name for this compound is
A) N-ethylpropanamide.
B) N-ethylacetamide.
C) pentanamide.
D) N,N-diethylacetamide.
E) ethylpropionamide
Organic Chemistry
HydrocarbonsUse the References to access important values needed for this question.
Determine the molecular and empirical formulas for the substance shown in the ball-and-stick model below.
Molecular Formula.
Empirical Formula
C = black
H = gray
Organic Chemistry
HydrocarbonsUsing the average atomic masses for each of the following elements, calculate the number of atoms present in each of the following samples.
a. 80.16 amu of calcium
atom(s)
b. 1471.2 amu of tungsten
atom(s)
c. 164.82 amu of manganese
atom(s)
Organic Chemistry
HydrocarbonsPredict the product(s) you would get when the following alkene reacts with H₂SO4 and H₂O:
If you expect a racemic mixture, draw both enantiomers.
Organic Chemistry
Hydrocarbons1. Draw structures for the products of the Diels-Alder reactions between
a) 1,3-cyclopentadiene and maleic anhydride.
b) 1,3-butadiene and trans-CH₂-CH=CH-CH=0.
c) anthracene and HO₂C-C=C-CO₂H.
Organic Chemistry
HydrocarbonsAdd one or more curved arrows to show the movement of electrons in the reaction: To draw the arrows, select More in the drawing menu, then select the appropriate curved arrow. Click on a bond or electron to start a curved arrow. Do not start from an atom. Use the select tool to move the arrow head and tail to the desired placement. The curved arrow changes from red to black when appropriately placed.
Organic Chemistry
HydrocarbonsGiven the following reaction below, how many moles of H 20 can be formed from 0.03352 moles of C 6H 14?
12 CO 2 (g) + 14 H 20 (g)
2 C 6H 14 (g) + 19 O 2 (g)
0.004789 mol
2.315 mol
0.3185 mol
4.261 mol
0.2347 mol
Organic Chemistry
HydrocarbonsDraw the molecule on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default.
Organic Chemistry
HydrocarbonsDraw the E isomer for
CH3CH₂CH=CHCH3
Draw the molecule on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default.
Organic Chemistry
HydrocarbonsDescribe how soap works in detail. What interactions are in play and between what?
Organic Chemistry
HydrocarbonsPredict the major product of this organic reaction:
CH3—CH=CH-CH3 + H2O -> H+ ?
Organic Chemistry
HydrocarbonsWhat is the name of the compound with the formula MgSO3 ?
What is the name of the compound with the formula KNO₂ ?
Organic Chemistry
HydrocarbonsThe structure below belongs to the class of organic compounds called.......and it's IUPAC name is CH3CH2CH2CCCH2CH3
A. Alkane; Dehydrogenated heptane
B. Alkene; 4- Heptene
C. Alkyne; 4- Heptyne
D. Alkyne; 3- Heptyne
E. Alkene; Hexene
Organic Chemistry
Hydrocarbons13. Select the statement that is most true regarding kinetic and thermodynamic
enolates.
a. kinetic enolates are formed with a higher energy of activation under
irreversible conditions relative to thermodynamic enolates.
b. kinetic enolates are formed with a higher energy of activation under
reversible conditions relative to thermodynamic enolates.
c. kinetic enolates are formed with a lower energy of activation under
reversible conditions relative to thermodynamic enolates.
d. kinetic enolates are formed with a lower energy of activation under
irreversible conditions relative to thermodynamic enolates.
Organic Chemistry
HydrocarbonsIdentify the type of transport described by each of the following:
a. an ion moves from low to high concentration in the cell.
b. carbon dioxide moves through a cell membrane.
Organic Chemistry
HydrocarbonsWhich of the following statements are true?
Select all that apply:
Covalent bonding forms as a result of a transfer of electrons from one atom
to another.
Covalent bonding forms when two atoms share electrons between them.
Covalent bonding typically forms between two metal atoms.
Covalent bonding typically forms between two nonmetal atoms.
Organic Chemistry
HydrocarbonsBe sure to answer all parts.
Write an expression for the equilibrium constant for the reaction.
2 NO(g) + O₂(g) = 2 NO₂(g)
Organic Chemistry
HydrocarbonsIf you pack a bag of potato chips for a snack on a plane ride, the bag appears to have inflated when you
take it out to open. If the initial volume of air in the bag was 380 mL at 760 mm Hg, and the plane is
pressurized at 630 mm Hg, what is the final volume (in mL) of the bag? The temperature and the
number of gas particles do not change.
Organic Chemistry
HydrocarbonsHow many moles of solute are contained in each solution?
a. 240 mL of a 0.34 M NaNO3 solution:
b. 79 mL of a 2.2 M HNO3 solution:
c. 6.9 L of a 4.9 M HCl solution:
Organic Chemistry
HydrocarbonsIf we compare a mole of carbon atoms to a mole of oxygen atoms, which
sample will contain more atoms?
Select the correct answer below:
the carbon sample
the oxygen sample
they will contain the same number of atoms
impossible to tell
|||
Organic Chemistry
HydrocarbonsA 10.0 g sample of a compound is found to contain 1.00 g carbon, 0.840 g
hydrogen, and 8.16 g chlorine. What is the compound's percent composition?
Select the correct answer below:
19.4% carbon, 31.9% hydrogen, 48.7% chlorine
51.0% carbon, 22.7% hydrogen, 26.3% chlorine
1.00% carbon, 0.840% hydrogen, 8.16% chlorine
10.0% carbon, 8.40% hydrogen, 81.6% chlorine
Organic Chemistry
HydrocarbonsFree radicals are defined as (A) with (B) one unpaired electron.
A: molecules B: at least
A: atoms B: at least
A: molecules or atoms B: at least
A: ions, molecules, or atoms B: at least
A: ions B: at most
A: molecules or ions B: at least
A: molecules, atoms, or ions B: at most
Organic Chemistry
HydrocarbonsFree radical are
in general, compared to non-radicals.
low in energy, unreactive, and stable.
low in energy, reactive, and unstable.
high in energy, reactive, and unstable.
high in energy, reactive, and stable.
high in energy, unreactive, and unstable.
Organic Chemistry
HydrocarbonsHow many grams of lead(II) chloride is produced if 13.87 g lead(II) nitrate combines with excess hydrochloric acid to produce lead(II)
chloride and nitric acid?
Pb(NO3)2 + HCI -> PbCl2 + HNO3 [unbalanced]
11.64 g
14.33 g
0.086 g
16.52 g
5.82 g
Organic Chemistry
Hydrocarbons1.49 moles of hydrogen gas are reacted with excess carbon monoxide according to the reaction below. If 15.5 grams of methanol (CH₂OH) are produced, what was the percent yield?
2 H₂(g) + CO(g) → CH₃OH(l)
(A) 59.1 %
(B) 64.9 %
(C) 68.5 %
(D) 72.3 %
(E) 79.19%
(F) 45.9 %
Organic Chemistry
HydrocarbonsThe reaction of CH3CH=CH-CH=CH₂ with excess bromine gives chiefly
a. 1,2-dibromo-3-pentene
b. 3,4-dibromo-1-pentene
C. 1,4-dibromo-2-pentene
d. a mixture of the above three compounds
e. none of the above three compounds
Organic Chemistry
HydrocarbonsAcetylene (C₂H₂) gas is often used in welding torches because of the very high heat produced when it reacts with oxygen (O₂) gas, producing carbon
dioxide gas and water vapor. Calculate the moles of acetylene needed to produce 0.075 mol of carbon dioxide. Be sure your answer has a unit symbol
necessary, and round it to the correct number of significant digits.
Organic Chemistry
HydrocarbonsWhich of the following pairs can be used to illustrate
the law of multiple proportions?
CO and CaCO3
H₂SO4 and H₂S
KCl and KClO₂
H₂O and C12H22O11
SO and SO₂
Organic Chemistry
HydrocarbonsWrite an expression for the equilibrium constant for the reaction.
CH₄(g) +2 Br₂(g) = CH₂Br₂(g) + 2HBr(g)
K=
Organic Chemistry
HydrocarbonsTreatment with O₃, followed by dimethyl sulfide (DMS), converts a trans-disubstituted alkene into a(n)
1. primary alcohol and aldehyde
2. allylic alcohol and ketone
3. secondary alcohol and carbon dioxide
4. tertiary alcohol and carboxylic acid
5. aldehyde and aldehyde
6. ketone and ketone
7. aldehyde and carbon dioxide
Organic Chemistry
HydrocarbonsA sample of oxygen gas is collected over water at 22°C and 98.67 kPa pressure. If the partial pressure of the water is 2.67 kPa, the partial pressure of the oxygen is -
96.00 kPa
101.33 kPa
98.66 kPa
93.33 kPa
Organic Chemistry
HydrocarbonsYou find an unknown liquid and determine that it has a density of 4.9 g/mL. Assume you fill a 820.0 mL container with this substance and are wondering how heavy it will be. What is the mass (in kilograms) of the liquid in the container, assuming it is filled to exactly 820.0 mL?
Organic Chemistry
HydrocarbonsMalonic acid is used in the manufacture of sleeping pills. A 5.500 g sample of malonic acid contains 1.904 g of carbon, 0.2131 g of hydrogen and the remainder is oxygen. Determine the empirical formula for malonic acid.
Organic Chemistry
HydrocarbonsAccording to the following balanced equation, the reaction of one mole of potassium permanganate would result in the production of how many moles of water?
16 HCI +2 KMnO4 --> 2 KCI + 2 MnCl₂ + 5 Cl₂ + 8 H₂O