Solutions Questions and Answers
Physical Chemistry
SolutionsThree saturated solutions have been prepared, all at 25°C.
• Solution A has 30 g of solid dissolved in 225 mL of water
• Solution B has 18.5 g of solid dissolved in 100 mL of water
• Solution C has 56 g of solid dissolved in 150 mL of water
Which solution is the most concentrated?
Physical Chemistry
SolutionsA saturated sodium chloride solution is prepared by dissolving 36 g solid NaCl into 100.0 g water
at 25 °C. Assuming a solution density of 1.20 g/mL at this temperature, calculate the molarity of
the saturated NaCl solution.
a. 0.00545 M NaCl
b.
0.36 M NaCl
c. 5.44 M NaCl
d. 6.16 M NaCl
e. 20.6 M NaCl
Physical Chemistry
SolutionsCalculate the pH for each of the cases in the titration of 25.0 mL of 0.220 M pyridine, C₂H₂N(aq) with 0.220 M HBr(aq). The
Kh of pyridine is 1.7 x 10-⁹.
before addition of any HBr
pH =
after addition of 12.5 mL of HBr
after addition of 24.0 mL of HBr
after addition of 25.0 mL of HBr
after addition of 35.0 mL of HBr
pH =
pH =
pH =
pH =
Physical Chemistry
SolutionsThe vapor pressure of liquid NH3 is 496.0 mmHg at a temperature of 231.4 K. The enthalpy of vaporization, AHvap, for this liquid is 23.3 kJ/mol.
What is the vapor pressure of NH3 at a temperature of 233.6 K, in mmHg?
______mmHg
Physical Chemistry
SolutionsWhich of the following aqueous solutions contains the greatest amount of ions or molecules dissolved in water?
750 mL of 0.75 M HBr
250 mL of 1.25 M K3PO4
250 mL of 0.5 M LiBr
1.5 L of 2.25 M C12H22011
2.0 L of 1.5 M K₂SO4
Physical Chemistry
Solutions0.15 M aqueous solution of potassium sulfate has on osmotic pressure of 8.21 atm at 27°C. Which of the following is correct about the properties of solution?
The value of Van't Hoff factor of K₂SO4 is 3.
The value of Van't Hoff factor for K₂SO4 is less than 3 due to partial dissociation of solute.
The value of Van't Hoff factor for K₂SO4 is more than 3 due to complete dissociation of solute.
The freezing point of solution would be more than 0°C.
Physical Chemistry
SolutionsA chemistry student weighs out 0.107 g of chloroacetic acid (HCH₂CICO₂) into a 250. mL volumetric flask and dilutes to the mark with distilled water. He
plans to titrate the acid with 0.1100 M NaOH solution.
Calculate the volume of NaOH solution the student will need to add to reach the equivalence point. Round your answer to 3 significant digits.
Physical Chemistry
SolutionsHow many grams of KMnO4 are required to make 0.653 L of a 1.83 M solution?
Physical Chemistry
Solutions(optional) A hospital saline solution is 0.90% NaCl. What is the molar concentration of
0.90% saline (58.44 g/mol) solution? (Assume the density of the solution is 1.01 g/mL.)
Physical Chemistry
SolutionsCore Chemistry Skill: Calculating the Molar Solubility
The solubility of a substance is the quantity that
dissolves to form a saturated solution, and it can be
represented by the solubility product expression (
Ksp). The solubility product expression is
equivalent to the product of the ion concentrations
after each is raised to a power that is equal to its
coefficient in the balanced equilibrium equation. For
an example, see the following reaction involving
calcium phosphate and its corresponding solubility
product expression:
Ca3(PO4)2 (s) = 3Ca²+ (aq) + 2PO4³- (aq)
Ksp = [Ca²+1³ [PO4³-1²
The molar solubility (S) of a slightly soluble salt is
the number of moles of solute that dissolve in 1 L
of solution and has the units M. For the example
above, every 1 mol of solute that dissolves
produces 3 mol of Ca²+ and 2 mol of PO4³ , so
the molar solubility is equivalent to
S=
[Ca²+]
3
(PO₁3-1
2
Part A
O MgCrO4
O CrO4²-
D Mg2+
If MgCrO4 were added to water to form 1 L of solution, the concentration of which species will be equal to the molar
solubility?
Check all that apply.
►'View Available Hint(s)
Submit
Part B Complete previous part(s)
14 of 17
Part C. Complete previous part(s)
Review | Constants | Periodic Table
Physical Chemistry
Solutions1. What is the concentration of ethanol (C₂H60) solution that was prepared by dissolving 50.500 g of
ethanol into water to a final volume of 750.0 mL? Assume the solution has a density of 1.20 g/mL.
Show all work.
a. % (m/m)
b. M
Physical Chemistry
SolutionsA solution with a total volume of 2.5 liters is composed of 31.4 grams of Na₂S in water. What
is the:
(a) Molarity of this solution? (1 pt)
(b) Osmolarity of this solution? (1 pt)
(c) the %mass/volume of this solution? (1 pt)
Physical Chemistry
SolutionsAn aqueous potassium iodate stock solution is made by dissolving 6.79 mol KIO, in sufficient water for the final volume of the
solution to be 3.20 L.
Calculate the molarity of the stock KIO, solution.
molarity of stock KIO, solution=
A 10.0 mL aliquot is removed from the described stock solution and diluted to a total volume of 100.0 mL.
Calculate the molarity of the dilute solution.
molarity of dilute KIO, solution=
M
M
Physical Chemistry
SolutionsCalculate the amount of solute, in grams or
milliliters, needed to prepare the following solutions:
Part B
401 g of a 4.0 % (m/m)KCl solution
Express your answer to two significant figures and include the appropriate units.
Value
Submit
HÅ
Part C
Units
Request Answer
Review | Constants I Periodi
?
295 mL of a 18 % (v/v) isopropyl alcohol solution
Express your answer to two significant figures and include the appropriate units.
Physical Chemistry
SolutionsShow all work. Round off answers to the nearest tenth place, except for gtt/min
calculations which must be rounded off to the nearest whole number.
1. Determine the time of infusion necessary for the IV if a client is receiving
535 ml D5W at 15 gtt/min and the drop factor is 10.
Physical Chemistry
SolutionsYou may want to reference (Page) Section 12.5
while completing this problem.
Calculate the final concentration of each of the
following.
▼ Part A
1.2 L of a 2.50 MHNO3 solution is added to water so that the final volume is 9.0 L.
Express your answer to two significant figures and include the appropriate units.
01
Value
Submit
μA
Part B
Units
Request Answer
Review I Constants I
?
Water is added to 0.50 L of a 6.9 MNaF solution to make 2.7 L of a diluted NaF solution.
Express your answer to two significant figures and include the appropriate units.
Physical Chemistry
SolutionsYou may want to reference (Page) Section 12.4
while completing this problem.
Calculate the mass percent (m/m) for the solute in
each of the following solutions.
▼
Express your answer using two significant figures.
m/m = 11 %
Submit
Previous Answers
Part C
✓ Correct
Since the mass of H₂O is given rather than the total mass of the solution, you must add the mass of KOH
given to find the total mass of the solution used in the denominator when calculating mass percent. Therefore,
mass% =
41.0 g of Na2CO3 in 277.5 g of Na2CO3 solution
Express your answer using two significant figures.
Review | Constants I Periodic Table
3.9g KOH
3.9g KOH+333g H₂O
x 100
Physical Chemistry
SolutionsYou may want to reference (Page) Section 12.6 while
completing this problem.
Answer the following questions for the reaction
NiCl2 (aq) + 2NaOH(aq) →>> Ni(OH)2 (s) + 2NaCl(aq)
▼
Part A
How many milliliters of 0.200 M NaOH solution are needed to react with 33.0 mL of a 0.360 M NiCl2 solution?
Express your answer with the appropriate units.
O
Value
Submit
μA
Part B
Units
Request Answer
Review | Constants I Periodic Table
?
How many grams of Ni(OH)2 are produced from the reaction of 46.0 mL of a 1.70 M NaOH solution and excess
NiCl₂?
Express your answer with the appropriate units.
Physical Chemistry
SolutionsAluminum reacts with oxygen to form aluminum oxide, Al2O3. Set up the calculation and solve for the mass ratio of aluminum
to oxygen in this compound.
Physical Chemistry
Solutions35.8 mL of aqueous 0.255 M Pb(NO3)2 is mixed with 19.1 mL of 0.415 M NaCl. The equation
for the precipitate reaction is: Pb(NO3)2 (aq) + 2 NaCl (aq) --> PbCl2 (s) +2 NaNO3(aq)
The concentration of NO3 ion in the reaction solution is
M.
Physical Chemistry
SolutionsUse the Henderson-Hasselbalch equation to calculate the pH of a buffer that contains 6.5 M
of the acid, HA, and 4.9 M of the conjugate base, A. Assume that the Ka for this acid is 1.6 x
10-6. Show your work and report the pH to two decimals. (4 pts)
Physical Chemistry
SolutionsDetermine whether aqueous solutions of the following salts would be acidic, basic, or neutral: (3
pts)
(a) LINO3
Oq bne Hq od: hqs egit
(b) NaF
(Prepared from LiOH and HNO3)
(c) NH4Cl
(Prepared from NaOH and HF)
(Prepared from NH3 and HCI)
10)
Physical Chemistry
SolutionsDescribe if the following reaction is spontaneous or non-spontaneous based on enthalpy, entropy and Gibbs energy: A H=8457J, A S
= 546J, and A G = 432J at room temperature
A) Spontaneous
B
Not spontaneous
Physical Chemistry
SolutionsWhat volume of a 0.200 M H2SO4 solution will completely neutralize 83.4 mL of 0.120 M NaOH solution?
H₂SO4 (aq) + 2 NaOH (aq) → Na2SO4 (aq) + 2 H₂O (1)
To receive any M
Physical Chemistry
Solutions5.57 A 2.200-g sample of quinone (C,H,O₂) is burned in a bomb calorimeter whose total heat
capacity is 7.854 kJ/°C. The temperature of the calorimeter increases from 23.44 to 30.57
*C. What is the heat of combustion per gram of quinone? Per mole of quinone?
Physical Chemistry
SolutionsIdentify the type of interactions involved in each of the following processes taking place during the dissolution of sodium chloride (NaCl) in water.
Drag the appropriate items to their respective bins.
►View Available Hint(s)
interactions formed during hydration
interactions involving dipole-dipole
attractions
Solvent-solvent interactions
interactions between the water
molecules
interactions involving ion-ion
attractions
Solute-solute interactions
interactions formed between the
sodium ions and the oxygen atoms of
water molecules
interactions between the ions of
sodium chloride
Solute-solvent interactions
Reset
Help
Physical Chemistry
SolutionsAn analytical chemist weighs out 0.087 g of an unknown monoprotic acid into a 250 mL volumetric flask and dilutes to the mark with distilled water. She then titrates this solution with 0.2000 M NaOH solution. When the titration reaches the equivalence point, the chemist finds she has added 4.8 mL of NaOH solution.
Calculate the molar mass of the unknown acid. Be sure your answer has the correct number of significant digits.
Physical Chemistry
SolutionsA chemistry student weighs out 0.133 g of lactic acid (HC₂H5O₂) into a 250. mL volumetric flask and dilutes to the mark with distilled water. He plans to titrate the acid with 0.1700M NaOH solution.
Calculate the volume of NaOH solution the student will need to add to reach the equivalence point. Round your answer to 3 significant digits.
Physical Chemistry
SolutionsAn aqueous solution at 25 °C has a OH concentration of 3.0 × 10 M. Calculate the H₂O* concentration. Be sure your answer has 2 significant digits.
Physical Chemistry
Solutions70.0 mL of 3.0 M sodium carbonate is added to 30.0 mL of 1.0 M sodium bicarbonate. Calculate the moles of sodium ions and the concentration of sodium ions in the final solution. (Enter answers without units)
moles of Nat in final solution:
molarity of Na in final solution:
Physical Chemistry
SolutionsThe solubility of glucose (C6H12O6) is 130 grams in 100 grams of water at 40°C. Which of the following situations would produce a saturated solution?
135 g of C6H12O6 in 100 g of water
100 g of C6H12O6 in 100 g of water
129 g of C6H12O6 in 100 g of water
125 g of C6H12O6 in 100 g of water
Physical Chemistry
SolutionsConsider a mixture of NaCl, albumin mixture, and starch mixtures in a dialyzing bag. The dialyzing bag is then immersed in distilled water. Which of the following actions should be taken to remove the most salt from the mixture?
Leave the dialyzing bag in the distilled water for an extended period of time.
Replace the dialyzing bag periodically.
Replace the water with fresh distilled water periodically.
Physical Chemistry
SolutionsThe solubility in water of ionic compound X is measured and found to be 0.142 g/mL at 10. °C. Calculate the volume of a saturated solution of Xin water that would contain 360. mg of X at this temperature.
Be sure your answer has the correct unit symbol and 3 significant digits.
Physical Chemistry
SolutionsA certain substance X condenses at a temperature of 149.3 °C. But if a 200. g sample of X is prepared with 7.75 g of urea ((NH2)2CO) dissolved in it, the sample is found to have a condensation point of 150.1 °C instead. Calculate the molal boiling point elevation constant Kb of X.
Round your answer to 1 significant digit.
Physical Chemistry
SolutionsWhat is the percent by mass of sodium chloride in a solution containing 25 g NaCl, 14 g KCl, and 5 g MgSO4 all dissolved in 175 g of water? Show all work and remember units are part of your answer.
Physical Chemistry
Solutions5.00 g of NaCl is dissolved in 25.0 mL of water. Then 4.00 mL of this solution is removed and mixed with 16.0 ml of water. What is the concentration of the final solution in molarity? (Enter answer without units)
Physical Chemistry
SolutionsWhat is the osmolarity of a solution containing 0.2 M NaNO3 and 0.3 M sucrose?
Select one:
0.7
0.0007
0.14
0.0014
Physical Chemistry
SolutionsA solution of potassium chloride contains 43.7 g of KCl dissolved in 0.50 L of solution. What
is the molarity of this solution? Show all work and remember units are part of your answer.
Physical Chemistry
SolutionsA sample of Ca (s) is added to water to make a 150. mL solution. Thymol blue indicator is added to the solution. The solution is then titrated with 1.00 M HCI. The initial reading of the burette is 5.00 mL before the titration, and when the color of the solution is observed to change from blue to yellow, the burette reads 38.91 mL. Determine the concentration (in mol/L) of hydroxide ions, [OH-], in the 150. mL solution. Do NOT include units in your answer. If you round during your calculation, be sure to keep at least three (3) decimal places. Report your answer to two (2) decimal places. Answer:
Physical Chemistry
SolutionsFor the reaction shown, calculate the theoretical
yield of product in moles for each of the initial
quantities of reactants.
2Mn(s) + 30₂(g) → 2MnO3(s)
0.164 mol Mn; 0.232 mol O₂
Express your answer in moles to three significant figures.
Theoretical yield =
Submit
Part D
VAZO
Request Answer
32.5 mol Mn; 51.8 mol O₂
Express your answer in moles to three significant figures.
Physical Chemistry
SolutionsMISSED THIS? Watch KCV 8.5. IWE 8.5; Read
Section 8.6. You can click on the Review link to
access the section in your e Text.
For the reaction shown, find the limiting reactant for
each of the following initial quantities of reactants.
2 Li (s) + Cl₂ (g) → 2 LiCl (s)
1.0 g Li; 1.0 g Cl₂
Express your answer as a chemical formula.
A chemical reaction does not occur for this question.
Part B
PATC ?
10.5 g Li; 37.2 g Cl₂
Express your answer as a chemical formula.
Physical Chemistry
Solutions(1 pts) 4a. Calculate the mass (in g) of NaCl needed to prepare 35.0 mL of a
0.90% w/v NaCl solution.
(1pts) 4b. Calculate the mass (in g) of NaCl needed to prepare 35.0 mL of a
20.0% w/v NaCl solution.
(3pts)
4c. Describe how you would make the solution for 4a. Be brief, but quantitative, in your answer.
Physical Chemistry
SolutionsFor the reaction shown, calculate how many moles of
each product form when the given amount of each
reactant completely reacts. Assume that there is more
than enough of the other reactant.
2 PbS (s) + 3 0₂ (g) → 2 PbO (s) +2 SO2 (g)
Physical Chemistry
SolutionsClassify the following pair of compounds. Select the single best answer.
O
O
O
identical molecules
stereoisomers
constitutional isomers
not isomers
and
CH3
23
Physical Chemistry
SolutionsA chemist prepares a solution of sodium carbonate (Na₂CO3) by measuring out 41.3 g of sodium carbonate into a 450. mL volumetric flask and filling the flask
to the mark with water.
Calculate the concentration in mol/L of the chemist's sodium carbonate solution. Round your answer to 3 significant digits.
Physical Chemistry
SolutionsCalcium chloride reacts with sodium phosphate to
form solid calcium phosphate and sodium chloride.
Balance the reaction below then answer the
questions following.
CaCl₂ (aq) + Na3PO4 (aq)
+ NaCl (aq)
Ca3(PO4)2 (s)
1. What is the reaction ratio between CaCl2 and
Ca3(PO4)2?
2. How much Na3PO4 is needed to form 10.0
grams of Ca3(PO4)2 ?
Physical Chemistry
SolutionsA chemist prepares a solution of iron(II) bromide (FeBr₂) by measuring out 150. g of iron(II) bromide into a 350. mL volumetric flask and filling the flask to the
mark with water.
Calculate the concentration in mol/L of the chemist's iron (II) bromide solution. Round your answer to 3 significant digits.
mol/L
x10
Physical Chemistry
SolutionsUpload your answers to the following problem by midnight tonig
Calcium chloride reacts with sodium phosphate to form solid ca
Ca3(PO4)2 (s) +
CaCl₂ (aq) + Na3PO4 (aq)
NaCl (aq)
1. What is the reaction ratio between CaCl₂ and Ca3(PO4)2?
2. How much Na3PO4 is needed to form 10.0 grams of Ca3(PO4
Physical Chemistry
SolutionsWhich sentence is capitalized correctly?
O The great wall of China is a series of stone and earthen fortifications in northern china.
The Great Wall of China is a series of stone and Earthen fortifications in Northern
China.
The Great Wall of China is a series of stone and earthen fortifications in Northern
China.
Physical Chemistry
SolutionsA biochemist carefully measures the molarity of sucrose in 97.8 mL of cell growth medium to be 90.5 mm.
Unfortunately, a careless graduate student forgets to cover the container of growth medium and a substantial amount of the solvent evaporates. The volume of the cell growth medium falls to 42.1 mL. Calculate the new molarity of sucrose in the cell growth medium.
Round each of your answers to 3 significant digits.