Pure water is saturated with pure solid AgCl A silver rod is

Last updated: 7/4/2023

Pure water is saturated with pure solid AgCl A silver rod is placed in the solution and the potential is measured against normal calomel electrode at 25 C This experiment is then repeated with a saturated solution of Agl If the difference in potential in the two cases is 0 177 V the ratio of solubility product Kp of AgCl and Agl at the temperature of the experiment is 10 Determine the value of x 6 Ag AgCl s Calomel Saturated solution Ag Ag1 s Calomel Saturated solution Eagl M E E EAgCl Ag This can be understood as Ag Agi s AgCl s Ag Or Ag Ag aq Ag aq Ag K AgI K AgCl 0 0 177 0 059 log 1 K AgCl sp K Agl 0 177 10 Ag Ag E