Classification of Elements and Periodicity Questions and Answers
Inorganic Chemistry
Classification of Elements and PeriodicityCalculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C.
Mg(s) | Mg2+ (aq, 2.74 M) Pb2+ (aq, 0.33 M) | Pb(s)
Mg2+ (aq) + 2e → Mg(s) E° = -2.37 V
E° = -0.13V
Pb2+ (aq) + 2e → Pb(s)
+2.71 V
+2.21 V
-1.94 V
-2.80 V
+2.62 V
Inorganic Chemistry
Classification of Elements and PeriodicitySuppose you assumed that the atmospheric pressure was one atmosphere instead of the
pressure that you recorded. Describe the error that would occur in reporting the molar
mass.
Inorganic Chemistry
Classification of Elements and Periodicity2. a) Draw the Lewis structure of sulfite (SO32-) with minimized formal charges on all atoms and assign
partial charges to each atom
b) How many electrons is around central S atom?
c) What is the hybridization of each atom?
Inorganic Chemistry
Classification of Elements and PeriodicityDo atoms generally get bigger or smaller as you go down a group in the periodic table?
Inorganic Chemistry
Classification of Elements and Periodicity"When filling orbitals of equal energy, electrons fill them singly first with parallel spins." This is known as:
Bohr's model.
Ground state.
Hund's rule.
Pauli exclusion principle.
Inorganic Chemistry
Classification of Elements and PeriodicityUse what you just observed to predict the following. How many drops of water can you put onto a penny before the water spills over the side? How many drops of alcohol before the alcohol spills over the side. Make a prediction, give it a try, and, most importantly, explain what's happening.
Inorganic Chemistry
Classification of Elements and PeriodicityWrite the complete electron configuration for the vanadium atom.
Using NOBLE GAS notation write the electron configuration for the copper atom.
Inorganic Chemistry
Classification of Elements and PeriodicityGreen light can have a wavelength of 541 nm. The energy of a photon of this light is:
1.07 x 10-^31 J
5.54 x 10^14 J
5.41 x 10^-7 J
2.72 x 10^18 J
3.67 x 10^-19 J
Inorganic Chemistry
Classification of Elements and PeriodicityA given set of p orbitals consists of ____ orbitals
1
2
3
4
5
Inorganic Chemistry
Classification of Elements and PeriodicityWhich of the following groups contains no ionic compounds?
PCl5, LiBr, Zn(OH)₂
HCN, NO₂, Ca(NO3)2
CH2O, H,S, NH
KOH, CC14, SF4
NaH, CaF2, N₂NH₂
Inorganic Chemistry
Classification of Elements and PeriodicityWhich of the following statements is (are) true?
I. An excited atom can return to its ground state by absorbing electromagnetic radiation.
II. The energy of an atom is increased when electromagnetic radiation is emitted from it.
III. The energy of electromagnetic radiation increases as its frequency increases.
IV. An electron in the n = 4 state in the hydrogen atom can go to the n=2 state by emitting electromagnetic radiation at the appropriate frequency.
V. The frequency and wavelength of electromagnetic radiation are inversely proportional to each other.
I, II, III
II, III, IV
I, II, IV
III, IV, V
III, V
Inorganic Chemistry
Classification of Elements and PeriodicityWhich of the following describes the compound BaCl₂?
Choose all answers that apply.
If the compound dissolved in water it would be a strong electrolyte.
The compound is ionic.
The compound would conduct electricity if molten.
The compound is molecular.
The compound would be expected to have a relatively low melting point.
Inorganic Chemistry
Classification of Elements and Periodicity(1) What is the name of the element with a valence electron configuration of 3s²3p6?
(2) What is the name of the element with a valence electron configuration of 2s²?
Inorganic Chemistry
Classification of Elements and Periodicity(1) What is the element with an electron configuration of 1s²2s²2p63s²3p64s²3d³?
(2) What is the element with an electron configuration of 1s²2s²2p63s²3p6?
Inorganic Chemistry
Classification of Elements and PeriodicityHow many 4d electrons would be predicted in the ground state for the following elements?
a. niobium
b. silver
c. rhenium
Inorganic Chemistry
Classification of Elements and PeriodicityComplete and balance the equations for the following reactions.
(Use the lowest possible coefficients. Be sure to specify states such as (aq) or (s). If a box is
not needed, leave it blank.)
K(s) +N₂ (9) ⇒____
K(s) + As(s) ⇒____
Inorganic Chemistry
Classification of Elements and PeriodicityWhat is the correct electron configuration of W²+?
[Xe]4f¹45d4
[Xe]4f145d6
[Xe] 6d46s²
[Xe]5f¹45d²6s²
[Xe] 4f145d652
Inorganic Chemistry
Classification of Elements and PeriodicityDetermine the formal charge on nitrogen in NO₂.
+1
+2
-1
0
Inorganic Chemistry
Classification of Elements and PeriodicityA local FM radio station broadcasts at a frequency of 93.8 MHz.
Calculate the wavelength at which it is broadcasting.
-¹)
Inorganic Chemistry
Classification of Elements and Periodicity(1) What is the complete ground state electron configuration for the silicon atom?
(2) What is the complete ground state electron configuration for the vanadium atom?
Inorganic Chemistry
Classification of Elements and PeriodicityDraw all resonance structures for the nitric acid molecule, HNO3 (NO₂OH).
Inorganic Chemistry
Classification of Elements and Periodicity(Do not use noble gas notation and enter the subshells in the order in which they are filled. Express your answer as a series of orbitals. For example, the electron
configuration of Li would be entered in complete form as 1s²2s¹.)
a. Lit
b. Tlt
c. Br
d. I
Inorganic Chemistry
Classification of Elements and PeriodicityWhat is the formal charge on each atom in OBr-?
A. = -1, Br=0
B. = -1, Br = +1
C. +1, Br = -2
D. O-2, Br = +1
E. = 0, Br = -1
Inorganic Chemistry
Classification of Elements and PeriodicityWhat is the electron-pair geometry for N in NO₂Cl?
Inorganic Chemistry
Classification of Elements and PeriodicityDraw all resonance structures for the sulfur trioxide molecule, SO3.
Inorganic Chemistry
Classification of Elements and PeriodicityA monatomic ion with a charge of +1 has an electronic configuration of 1s²2s²2p 3s²3p64s²3d¹04p6.
This ion is a(n)
What is the formula of the ion?
What is the chemical symbol of the noble gas this ion is isoelectronic with?
Inorganic Chemistry
Classification of Elements and PeriodicityA monatomic ion with a charge of -2 has an electronic configuration of 1s²2s²2p 3s²3p64s²3d¹04p6
This ion is a(n)
What is the chemical symbol of the noble gas this ion is isoelectronic with?
Inorganic Chemistry
Classification of Elements and Periodicitya. Give the expected hybridization of the central atom of XeF4.
b. Give the expected hybridization of the central atom of SO3.
Inorganic Chemistry
Classification of Elements and PeriodicityA. What is the hybridization of the central atom in XeF4?
Hybridization =
What are the approximate bond angles in this substance ?
Bond angles =
B. What is the hybridization of the central atom in IBr3?
Hybridization =
What are the approximate bond angles in this substance ?
Bond angles =
Inorganic Chemistry
Classification of Elements and Periodicity9. A water solution of sulfuric acid has a density of 1.67 grams/mL and is 75 percent
H₂SO4 by mass. How many moles of H₂SO4 are contained in 400 mL of this solution?
Inorganic Chemistry
Classification of Elements and PeriodicityA sample of mercury (II) bromide, HgBr2, weighs 8.65 grams. How many moles are in this sample?
Inorganic Chemistry
Classification of Elements and PeriodicityA sample of oxygen gas, O2 weighs 28.4 grams. How many molecules of O2 and how many atoms of O are present in this sample?
Inorganic Chemistry
Classification of Elements and Periodicitya. Identify the element that has atomic nuclei represented by nucleus 1.
b. Explain why nucleus 2 and nucleus 4 represent the nuclei of two different isotopes of the same element.
c. Identify the nucleus above that is found in an atom that has a stable valence electron configuration.
Inorganic Chemistry
Classification of Elements and PeriodicityCalculate ΔH for the reaction:
2NH3 (g) + O2(g) → N₂H₁ (l) + H₂O(l)
given the following data:
2NH3(g) + 3N₂O(g) → 4N2 (g) + 3H₂O(l) ΔH-1010kJ
N₂O(g) + 3H₂(g) → N₂H4 (1) + H₂O(l) ΔH = -317 kJ
N₂H4 (l) + O2(g) → N₂(g) + 2H₂O(l) ΔH=-623 kJ
H2(g) + 1/2 O2(g) → H₂O(l) ΔH-286 kJ
Inorganic Chemistry
Classification of Elements and PeriodicityWhich of the following statements about chemical formulas is FALSE?
The subscripts represent the relative mass of each type of atom in the compound.
The subscripts do not change for a given compound.
The subscripts represent the relative number of each type of atom in the compound.
Different compounds made of the same elements have different subscripts.
Inorganic Chemistry
Classification of Elements and PeriodicityDoes a reaction occur when aqueous solutions of iron(III) sulfate and calcium chloride are combined?
yes/no
If a reaction does occur, write the net ionic equation.
Inorganic Chemistry
Classification of Elements and PeriodicityMethanol (wood alcohol) is a fuel that can be made from biomass (such as cellulose obtained from aspen trees). Methanol can also be made from natural gas. The overall synthesis reaction for the latter case is
CH4(g) + H₂O() → CH₂OH(1) + H₂(g), ΔHo = ?
Use the reactions below and Hess' law to predict the standard molar enthalpy of synthesis of methanol by this process.
CO(g) + 3 H₂(g) -> CH4(g) + H₂O (l) ΔH = -249.9 kJ
CO(g) + 2 H₂(g) → CH₂OH (l) ΔH"=-128.7 kJ
Inorganic Chemistry
Classification of Elements and PeriodicityThe element sodium forms a ____ with the charge ___
The symbol for this ion is ___ and the name is ___ ion.
The number of electrons in this ion is ____
Inorganic Chemistry
Classification of Elements and PeriodicityWhich of the following statements about the mole is FALSE?
One mole of water contains 1/2 mole of oxygen atoms.
One mole of a monatomic element has a mass equal to its atomic mass expressed in grams.
A mole of a monatomic element corresponds to one Avogadro's number of atoms.
One mole of atoms makes up an amount of atoms that can be seen with the naked eye.
Inorganic Chemistry
Classification of Elements and PeriodicityConsider three 1-L flasks at STP. Flask A contains NH3 gas, flask B contains NO₂ gas, and flask C contains N₂ gas. Which contains the largest number of molecules?
Flask C
Flask A
Flask B
All are the same.
More information is need to answer this.
Inorganic Chemistry
Classification of Elements and PeriodicityA newly discovered gas has a density of 2.33 g/L at 25.0 °C and 709 mm Hg. What is the molar mass of the gas?
61.1 g/mol
5.13 g/mol
805 g/mol
11.3 g/mol
Inorganic Chemistry
Classification of Elements and PeriodicityIt is desired to inflate a baggie with a volume of 912 milliliters by filling it with neon gas at a pressure of 0.965 atm and a temperature of 309 K. How many grams of Ne gas are needed?
Inorganic Chemistry
Classification of Elements and PeriodicityWhat volume of hydrogen gas is produced when 58.4 g of iron reacts completely according to the following reaction at 25 °C and 1 atm?
iron (s) + hydrochloric acid(aq)-iron(II) chloride (aq) + hydrogen(g)
Inorganic Chemistry
Classification of Elements and PeriodicityA 5.78 gram sample of neon gas has a volume of 912 milliliters at a pressure of 3.95 atm. The temperature of the Ne gas sample is
Inorganic Chemistry
Classification of Elements and PeriodicityThe name of the 11th most abundant gas in dry air at sea level is
Inorganic Chemistry
Classification of Elements and PeriodicityWhich of the following would represent the greatest pressure?
15.5 in Hg
0.660 atm
0379 mmHg
067055 Pa
12.9 psi
Inorganic Chemistry
Classification of Elements and PeriodicityA sample of nitrogen gas at a pressure of 0.615 atm and a temperature of 210 °C, occupies a volume of 574 mL. If the gas is cooled at constant pressure until its volume is 485 mL, the temperature of the gas sample will be ___ °C.
Inorganic Chemistry
Classification of Elements and PeriodicityA sample of carbon dioxide gas collected at a pressure of 324 mm Hg and a temperature of 284 K has a mass of 54.6 grams. The volume of the sample is ___ L.